EFFECT OF ROTATION OF SINGLE CRYSTALS
EFFECT OF ROTATION OF SINGLE CRYSTALS
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Effect of rotation of single crystal |
Recently, for the first time the dynamics of a cholesteric phase induction was investigated on dissolution of the single crystals (various chiral compounds) at the nematic droplet and the new effect of the crystal rotation has been discovered. |
Scheme of observation of the effect of rotation of small single crystal: |
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During dissolution of a single crystal of chiral compounds at the top a nematic droplet the correlation between the rotation direction and screw sense of the cholesteric helix was found:
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It was experimentally shown, that the angular velocity of the rotation of crystal of the chiral dopant dependent on:
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In addition, it was found, that
dissolution of a single crystal of racemic mixture of enantiomers at the top a nematic droplet occurs without
rotation. |
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For systematic series of dopants (e.g. cholesterol esters), the angular velocity ν was:
It can be argued that the obtained results:
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